Poly[bis­(μ-hemihydrogen 2-phenyl­quinoline-4-carboxyl­ato-κ2 N,O)silver(I)]

نویسندگان

  • Xiutang Zhang
  • Peihai Wei
  • Bin Li
چکیده

In the title compound, [Ag(C(16)H(10.5)NO(2))(2)], the Ag(I) cation (site symmetry 2) is coordinated by two N atoms in a near-linear AgN(2) arrangement. Two carboxyl-ate O atoms from two additional 2-phenyl-quinoline-4-carboxyl-ate ligands form long Ag-O bonds [2.6585 (17) Å], resulting in a distorted square-planar arrangement. The bridging ligands result in infinite corrugated sheets propagating in (010). An O-H⋯O hydrogen bond, disordered about a twofold axis, completes the structure.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Poly[bis­(μ-hemihydrogen 2-phenyl­quinoline-4-carboxyl­ato-κ2 N,O)silver(I)]. Corrigendum

The affiliation of one of the authors in the paper by Zhang, Wei & Li [Acta Cryst. (2009), E65, m223] is corrected.[This corrects the article DOI: 10.1107/S1600536809001184.].

متن کامل

Bis(μ-2-phenyl­quinoline-4-carboxyl­ato)-κ3 O,O′:O;κ3 O:O,O′-bis­[(2,2′-bipyridine-κ2 N,N′)(2-phenyl­quinoline-4-carboxyl­ato-κ2 O,O′)cadmium(II)]

The neutral binuclear title complex, [Cd(2)(C(16)H(10)NO(2))(4)(C(10)H(8)N(2))(2)], is centrosymmetric, with the inversion center generating the central (μ-O)(2)Cd(2) bridge. The Cd(II) ion is in a strongly distorted CdN(2)O(5) penta-gonal-bipyramidal geometry, defined by two N atoms from one 2,2'-bipyridine ligand and five O atoms from three 2-phenyl-quinoline-4-carboxyl-ate ligands, one monod...

متن کامل

Poly[[[silver(I)-μ-1,4-bis­[(imidazol-1-yl)meth­yl]benzene-κ2 N 3:N 3′-silver(I)-μ-1,4-bis­[(imidazol-1-yl)meth­yl]benzene-κ2 N 3:N 3′] 4,4′-diazenediyldibenzoate] dihydrate]

In the title compound, [Ag(2)(C(14)H(14)N(4))(2)](C(14)H(8)N(2)O(4))·2H(2)O, each of the two unique Ag(+) ions is two-coordinated by two N atoms from two different 1,4-bis-[(imidazol-1-yl)meth-yl]benzene ligands in an almost linear fashion [N-Ag-N = 170.34 (10) and 160.25 (10)°]. The 4,4'-diazenediyldibenzoate anions do not coordinate to Ag. O-H⋯O hydrogen bonds stabilize the crystal structure.

متن کامل

Tetra­kis(μ-2-phenyl­quinoline-4-carboxyl­ato-κ2 O:O′)bis­[(methanol-κO)copper(II)]

The title complex, [Cu(2)(C(16)H(10)NO(2))(4)(CH(3)OH)(2)], consists of centrosymmetric wheel-shaped dinuclear neutral mol-ecules in which each Cu(II) atom is coordinated in a slightly distorted square-pyramidal geometry by four O atoms of carboxyl-ate groups from different ligands at the basal plane and an O atom of a methanol mol-ecule at the axial position. In the crystal, the dinuclear comp...

متن کامل

Poly[[μ-aqua-bis­(μ-4,4′-bipyridine-κ2 N:N′)bis­(μ-3-hy­droxy­adamantane-1-carboxyl­ato-κ2 O:O′)bis­(3-hy­droxy­adamantane-1-carboxyl­ato-κO)dicobalt(II)] hepta­hydrate]

The title coordination compound, {[Co(C(11)H(15)O(3))(4)(C(10)H(8)N(2))(2)(H(2)O)]·7H(2)O}(n), consists of a pair of Co(II) atoms, four 3-hy-droxy-adamantane-1-carboxyl-ate anions (L), one water mol-ecule, two bridging 4,4'-bipyridine (4,4'-bpy) ligands and seven uncoordinated water mol-ecules. Both of the Co(II) ions are coordinated in a distorted octa-hedral geometry. Four L ligands bind to e...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009